Principles of Physical Chemistry

Principles of Physical Chemistry

Structure of Atoms, Molecules, and Solids

Foersterling, Horst-Dieter; Kuhn, Hans; Waldeck, David H.

John Wiley & Sons Inc

10/2024

1040

Dura

Inglês

9781119852667

Pré-lançamento - envio 15 a 20 dias após a sua edição

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Preface Third Edition xxv

Acknowledgement xxvii

List of Symbols xxix

About the Companion Website xxxi

Introduction xxxiii

1 Wave-Particle Duality 1

2 Essential Aspects of Structure and Bonding 17

3 Schroedinger Equation 36

4 Hydrogen Atom 67

5 Atoms and Variational Principle 86

6 A Quantitative View of Chemical Bonding 123

7 Bonding Described by Electron Pairs and Molecular Orbitals 142

8 Molecules with ?-Electron Systems 177

9 Absorption of Light 208

10 Emission of Light 262

11 Nuclei: Particle and Wave Properties 282

12 Nuclear Spin 330

13 Solids and Intermolecular Forces 345

14 Thermal Motion of Molecules 376

15 Energy Distribution in Molecular Assemblies 411

16 Work w, Heat q, and Internal Energy U 453

17 Reversible Work wrev, Reversible Heat qrev, and Entropy S 482

18 General Conditions for Spontaneity and its Application to Equilibria of Ideal Gases and Dilute Solutions 525

19 Formal Thermodynamics and Its Application to Phase Equilibria 567

20 Real Gases 590

21 Real Solutions 612

22 Reaction Equilibria in Aqueous Solutions and Biosystems 633

23 Chemical Reactions in Electrochemical Cells 658

24 Chemical Kinetics 689

25 Transition States and Chemical Reactions 740

26 Macromolecules 775

27 Organized Molecular Assemblies 809

28 Supramolecular Machines 835

29 Origin of Life. Matter Carrying Information 899

Appendices 930

A Data Tables 930

B Mathematical Tables 946

C Mathematical Miscellany 952

Index 979
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quantum mechanics; electronic structure; de Broglie; variational principle; Pauli exclusion; spin-orbit interactions; atomic spectroscopy; quantum confinement; quantum dots; quantum beats; molecular structure; chemical bonding; electron tunneling