Catalytic Asymmetric Synthesis

Preface ix

Preface to the First Edition xi

List of Contributors xiii

Part I Asymmetric Organocatalysis 1

1 Asymmetric Enamine and Iminium Ion Catalysis 3
Yujiro Hayashi

2 Asymmetric Acid Organocatalysis 29
Takahiko Akiyama

3 Asymmetric Base Organocatalysis 81
Azusa Kondoh and Masahiro Terada

4 Asymmetric Phase-Transfer and Ion-Pair Organocatalyses 117
Edward Miller, Patrick J. Moon, and F. Dean Toste

5 Asymmetric Peptide Catalysis 157
Kazuaki Kudo

6 Asymmetric Carbene Catalysis: A Brief Highlight of Developments in the Past Decade 199
Jia-Lei Yan, Hongling Wang, and Yonggui Robin Chi

7 Asymmetric Hypervalent Iodine Catalysis 243
Muhammet Uyanik and Kazuaki Ishihara

Part II Asymmetric Photochemical Reactions and Photoredox Catalysis 277

8 Asymmetric Visible-Light Photoredox Catalysis 279
Jiyuan Lyu, Aurelie Claraz, and Geraldine Masson

9 Asymmetric Photoredox Reactions without Photocatalysts 329
Dengke Ma, Thomas Hin-Fung Wong, and Paolo Melchiorre

10 Enantioselective Photochemical [2+2] Cycloaddition Reactions 355
Freya M. Harvey and Thorsten Bach

Part III Asymmetric Synthesis Through C-H Bond Activation 385

11 Asymmetric C-H Functionalization of C(sp2)-H Bond 387
Uttam Dhawa, Tomasz Wdowik, and Lutz Ackermann

12 Asymmetric C-H Functionalization of C(sp3)-H Bond 429
Xiao Zhang, Yangyang Shen, Eva Bednar?ova, and Tomislav Rovis

Part IV Asymmetric Synthesis Through Carbon-Halogen Bond Formation and Enzyme Catalysis 491

13 Asymmetric Carbon-Halogen Bond Forming Reactions (Excluding C-H Activation Processes) 493
Santos Fustero, Attila M. Remete, Lorand Kiss, Mercedes Medio-Simon, Jorge Escorihuela, and Daniel M. Sedgwick

14 Enzyme-Catalyzed Asymmetric Synthesis 531
Gonzalo de Gonzalo and Andres R. Alcantara

Part V Asymmetric Hydrogenation 559

15 Asymmetric Hydrogenation 561
Anton Vidal-Ferran, Arnald Grabulosa, Xavier Verdaguer, and Antoni Riera

Part VI Asymmetric Carbon-Carbon Bond Forming Reactions Chapter 617
16 Asymmetric Nucleophilic Addition to Ketones and Ketimines and Conjugate

Addition Reactions 619
Luo Ge and Syuzanna R. Harutyunyan

17 Asymmetric Allylic Alkylation, Allylation, and Related Reactions 661
Tyler J. Fulton, Yun E. Du, and Brian M. Stoltz

18 Asymmetric Carbometallations Including Carbocyclizations 705
Ken Tanaka

Part VII Asymmetric Synthesis of Non-Centro- Chiral Compounds 727

19 Asymmetric Synthesis of Axially Chiral Compounds 729
Shaohua Xiang, Jun Kee Cheng, and Bin Tan

20 Asymmetric Synthesis of Planar Chiral and Helically Chiral Compounds 769
Takanori Shibata

Part VIII Asymmetric Polymerization 803

21 Asymmetric Polymerization 805
Jie Li and Xiao-Bing Lu

Part IX Asymmetric Catalysis in Continuous-Flow System 831

22 Continuous-Flow Chemistry in Catalytic Asymmetric Synthesis 833
Haruro Ishitani, Yuki Saito, and Shu? Kobayashi

Index 869

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• Química orgânica

chiral catalyst molecules; asymmetric organic synthesis; catalytic asymmetric synthesis; metal catalysis; organocatalysis, photoredox catalysis; enzyme catalysis; C-H bond functionalization; non-centro-chiral compounds; flow reactions; hydrogenation; carbon-carbon bond formation reactions; carbon-halogen bond formation reactions; polymerization; carbon-carbon bond-forming reactions;